报告题目:The Dynamics of Gel Swelling
报告时间:2023年7月14日(周五)下午15:30
报告地点:3号楼307会议室
报告人:满兴坤 教授
邀请人:土井正男 研究员
简历:北京航空航天大学物理学院,教授,博导。2004年本科毕业于北京科技大学应用物理系。2009年博士毕业于中科院化学所。2009-2011年以色列特拉维夫大学博士后。2011-2013年美国加州大学圣芭芭拉分校博士后。2013年开始在北航工作。主持和参与多项国家自然基金委项目:国家优秀青年基金(2018年)、重点、中以国际合作等,并获得北航青年拔尖人才计划资助。在Phys. Rev. Lett., Phys. Rep., Adv. Mater., 和Macromolecules等期刊上发表多篇SCI论文。《Chinese Chemical Letters》第六届编委会委员、《Advanced Physics Research》第一届编委会委员、《Macromolecular Theory and Simulations》编委会委员。
摘要:When a polymer gel absorbs solvent from surrounding, stress field is created in the gel, and this causes complex dynamics of the swelling behavior. For example, a thin gel sheet bends as liquid penetrates from one side of the surface. We develop a diffusio-mechanical theory for gel dynamics. We calculate the time dependence of the bending behaviors for two types of gels. (a) a free gel that can swell in all directions freely, and (b) a bound gel the bottom surface of which is adhered to a plastic film which can bend but cannot stretch. The theory shows that the bending behaviors of the two gels are distinctively different. The free gel bends as the liquid penetrates, and takes a maximum curvature, and then slowly bends back to take the original flat shape. On the other hand, the bound gel keeps bending, and gets an equilibrium state in a bent configuration. For gel swelling, we show that (a) while the macroscopic thickness and the radius of the gel increases monotonically in time, the gel is compressed near the mid-plane, and that (b) while the swelling time depends on the shear modulus $G$ of the gel, its dependence is weak, and the time is mainly determined by the friction constant of the gel network and the osmotic bulk modulus of the gel. We also show that these characteristic features are reproduced accurately by a simple variational calculation for the gel deformation. An analytical expression is given for the gel dynamic time.